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Accessibility information
Author(s):   Cavallotti, C.; Mancarella, S.; Rota, R.; Carra, S.
Title:   Conversion of C5 into C6 cyclic species through the formation of C7 intermediates
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   3959 - 3969
Year:   2007
Reference type:   Journal article
Squib:   2007CAV/MAN3959-3969

Reaction:   Toluene·CH3 + Phenyl
Reaction order:   1
Temperature:   1000 - 2500 K
Rate expression:   2.22x1018 [s-1] (T/298 K)-1.73 e-435973 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 4.59E-6
1100 4.58E-4
1200 2.09E-2
1300 5.25E-1
1400 8.23E0
1500 8.87E1
1600 7.05E2
1700 4.36E3
1800 2.19E4
1900 9.25E4
2000 3.36E5
2100 1.08E6
2200 3.09E6
2300 8.06E6
2400 1.94E7
2500 4.32E7