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Author(s):   Chaban, O.Y.; Dominguez, R.M.; Herize, A.; Tosta, M.; Cuenca, A.; Chuchani, G.
Title:   Kinetic and mechanism of the homogeneous, unimolecular elimination of alpha,beta-unsaturated alclehydes in the gas phase
Journal:   J. Phys. Org. Chem.
Volume:   20
Page(s):   307 - 312
Year:   2007
Reference type:   Journal article
Squib:   2007CHA/DOM307-312

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2007CHA/DOM307-312   (E)-CH3CH=CHCHOCH3CH=CH2 + CO  654 - 704   1.51E13       2.12E05      1
  2007CHA/DOM307-312   C6H5CH=C(CH3)COH → Products + CO  714 - 763   1.69E13       2.35E05      1

Search returned 2 records.