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Author(s):   Dollet, A.; de Persis, S.
Title:   Pressure-dependent rate coefficients of chemical reactions involving Si2H4 isomerization from QRRK calculations
Journal:   J. Anal. Appl.Pyrolsis
Volume:   80
Page(s):   460 - 470
Year:   2007
Reference type:   Journal article
Squib:   2007DOL/DEP460-470

Reaction:   Si + SiH4H2 + SiSiH2
Reaction order:   2
Temperature:   300 - 1600 K
Rate expression:   2.34x10-14 [cm3/molecule s] (T/298 K)3.89 e-1101 [J/mole]/RT
Category:  Theory
Data type:   Other theoretical
Pressure dependence:   Rate constant is low pressure limit
Comments:   QRRK modeling.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.54E-14
400 5.28E-14
500 1.34E-13
600 2.85E-13
700 5.36E-13
800 9.23E-13
900 1.49E-12
1000 2.27E-12
1100 3.33E-12
1200 4.72E-12
1300 6.50E-12
1400 8.74E-12
1500 1.15E-11
1600 1.49E-11