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Title: H atom yields from the reactions of CN radicals with C2H2, C2H4, C3H6, trans-2-C4H8, and iso-C4H8
Journal: J. Phys. Chem. A
Volume: 111
Page(s): 6679 - 6692
Year: 2007
Reference type: Journal article
Squib: 2007GAN/GLO6679-6692
Reaction:
CN + C2H4 → CH2CHCN + H·
Reaction order:
2
Temperature:
298
K
Pressure: 3.33E-2 - 0.40 bar
Rate expression:
3.21x10-10 [±6.2x10-11 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
Rate constant was measured by monitoring H.
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