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Accessibility information
Author(s):   Hermans, I.; Jacobs, P.; Peeters, J.
Title:   The formation of byproducts in the autoxidation of cyclohexane
Journal:   Chem. Euro. J.
Volume:   13
Page(s):   754 - 761
Year:   2007
Reference type:   Journal article
Squib:   2007HER/JAC754-761

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2007HER/JAC754-761   ·CH2(CH2)4CHO → CH3(CH2)4C(·)=O                     1
    2007HER/JAC754-761   ·OOCH2(CH2)4CHO + Cyclohexane → HOOCH2(CH2)4CHO + Cyclohexyl                     2
    2007HER/JAC754-761   ·OOCH2(CH2)4CHO → HOOCH2(CH2)4C(·)=O                     1
    2007HER/JAC754-761   HOOCH2(CH2)4C(·)=O → ·OCH2(CH2)4C(O)OH                     1
    2007HER/JAC754-761   HOOCH2(CH2)4C(·)=O → ·CH2CH2CH2CH2CH2OOH + CO                     1
    2007HER/JAC754-761   n-C3H7OH + Cyclohexyldioxyl → Cyclohexyl hydroperoxide + C2H5CH(·)OH                     2
    2007HER/JAC754-761   O=CH(CH2)4C(O)OH + Cyclohexyldioxyl → O=C(·)(CH2)4C(O)OH + Cyclohexyl hydroperoxide                     2
    2007HER/JAC754-761   CH3OOH + CH3COCH3C(O)OH + CH3                     2
    2007HER/JAC754-761   ·OOC(O)(CH2)4C(O)OH + Cyclohexane → HOOC(O)(CH2)4C(O)OH + Cyclohexyl                     2
    2007HER/JAC754-761   HOOC(O)(CH2)4C(O)OH + Cyclohexyl → ·OC(O)(CH2)4C(O)OH + Cyclohexanol                     2
    2007HER/JAC754-761   ·OC(O)(CH2)4C(O)OH → ·CH2(CH2)3C(O)OH + CO2                     1
    2007HER/JAC754-761   ·OOC(O)(CH2)4C(O)OH + Cyclohexanone → cyc-C6H10(O·)OOC(O)(CH2)4C(O)OH                     2
    2007HER/JAC754-761   cyc-C6H10(O·)OOC(O)(CH2)4C(O)OH → ·CH2(CH2)4C(O)OOC(O)(CH2)4C(O)OH                     1
    2007HER/JAC754-761   ·CH2(CH2)4C(O)OOC(O)(CH2)4C(O)OH → ·OC(O)(CH2)4C(O)OH + 2-Oxepanone                     1

Search returned 14 records.