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Accessibility information
Author(s):   Irikura, K.K.; Francisco, J.S.
Title:   Competition between hydrogen abstraction and halogen displacement in the reaction of Br with CH3I, CH3Br, and CH3Cl
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   6852 - 6859
Year:   2007
Reference type:   Journal article
Squib:   2007IRI/FRA6852-6859

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2007IRI/FRA6852-6859   CH3I + Br·CH3Br + I  298   5.90E-23              2
  2007IRI/FRA6852-6859   CH3Br + Br·CH3Br + Br·  298   1.20E-28              2
  2007IRI/FRA6852-6859   CH3Cl + Br·CH3Br + ·Cl  298   2.50E-34              2
  2007IRI/FRA6852-6859   CH3I + Br·HBr + ·CH2I  298   4.10E-22              2
  2007IRI/FRA6852-6859   CH3Br + Br·HBr + ·CH2Br  298   1.80E-22              2
  2007IRI/FRA6852-6859   CH3Cl + Br··CH2Cl + HBr  298   6.00E-22              2
  2007IRI/FRA6852-6859   ·CH2Cl + HBrCH3Cl + Br·  298   5.70E-14              2
  2007IRI/FRA6852-6859   HBr + ·CH2BrCH3Br + Br·  298   9.10E-14              2
  2007IRI/FRA6852-6859   HBr + ·CH2ICH3I + Br·  298   3.40E-13              2
  2007IRI/FRA6852-6859   CH3Br + ·ClCH3Cl + Br·  298   1.30E-24              2
  2007IRI/FRA6852-6859   CH3Br + ICH3I + Br·  298   1.30E-32              2

Search returned 11 records.