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Author(s):   Li, J.;Zhao, Z.W.;Kazakov, A.;Chaos, M.;Dryer, F.L.;Scire, J.J.
Title:   A comprehensive kinetic mechanism for CO, CH2O, and CH3OH combustion
Journal:   Int. J. Chem. Kinet.
Volume:   39
Page(s):   109 - 136
Year:   2007
Reference type:   Journal article
Squib:   2007LI/ZHA109-136

Reaction:   CO + ·OHCO2 +
Reaction order:   2
Temperature:   850 - 950 K
Pressure:  1.52 - 6.08 bar
Rate expression:   1.76x10-14 [cm3/molecule s] (T/298 K)1.89 e4847 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Experimental procedure:   Stirred flow reactor(PSR etc.)
Excitation technique:   Thermal
Time resolution:   In both real time and by end product analysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
850 2.53E-13
875 2.62E-13
900 2.71E-13
925 2.81E-13
950 2.90E-13