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Author(s):   Mousavipour, S.H.; Saheb, V.; Pirhadi, F.; Dehbozorgi, M.R.
Title:   Experimental and theoretical study on the kinetics and mechanism of thermal decomposition of 1,2-dichloroethane
Journal:   J. Iran. Chem. Soc.
Volume:   4
Page(s):   279 - 298
Year:   2007
Reference type:   Journal article
Squib:   2007MOU/SAH279-298

Reaction:   CH2ClCH2ClCH2=CHCl + HCl
Reaction order:   1
Temperature:   849 - 1064 K
Pressure:  1.33E-2 - 0.40 bar
Rate expression:   4.2x1013 [s-1] e-235700 [J/mole]/RT
Category:  Experiment
Data type:   High or low pressure extrapolation
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Stirred flow reactor(PSR etc.)
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Troe extrapolation of experimental pyrolysis data.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
849 1.32E-1
850 1.38E-1
875 3.57E-1
900 8.79E-1
925 2.06E0
950 4.61E0
975 9.91E0
1000 2.05E1
1025 4.09E1
1050 7.91E1
1064 1.13E2