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Author(s):   Papadimitriou, V.C.; Papanastasiou, D.K.; Stefanopoulos, V.G.; Zaras, A.M.; Lazarou, Y.G.; Papagiannakopoulos, P.
Title:   Kinetic study of the reactions of Cl atoms with CF2CH2CH2OH, CF3CF2CH2OH, CHF2CF2CH2OH, and CF3CHFCF2CH2OH
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   11608 - 11617
Year:   2007
Reference type:   Journal article
Squib:   2007PAP/PAP11608-11617

Reaction:   CF3CH2CH2OH + Cl → Products + HCl
Reaction order:   2
Temperature:   273 - 363 K
Pressure:  2.67E-3 bar
Rate expression:   4.42x10-11 [±4.8x10-12 cm3/molecule s] e-2120 [±166 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 1.74E-11
275 1.75E-11
300 1.89E-11
325 2.02E-11
350 2.13E-11
363 2.19E-11