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Accessibility information
Author(s):   Srinivasan, N.K.; Su, M.C.; Michael, J.V.
Title:   Reflected shock tube studies of high-temperature rate constants for OH+C2H2 and OH+C2H4
Journal:   Phys. Chem. Chem. Phys.
Volume:   9
Page(s):   4155 - 4163
Year:   2007
Reference type:   Journal article
Squib:   2007SRI/SU4155-4163

Reaction:   C2H4 + ·OH → Products
Reaction order:   2
Temperature:   1463 - 1931 K
Pressure:  2.18E13 - 3.14E13 bar
Rate expression:   1.02x10-9 [±5.8x10-10 cm3/molecule s] e-61619 [±7242 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1463 6.44E-12
1475 6.71E-12
1500 7.29E-12
1525 7.91E-12
1550 8.55E-12
1575 9.23E-12
1600 9.93E-12
1625 1.07E-11
1650 1.14E-11
1675 1.22E-11
1700 1.30E-11
1725 1.39E-11
1750 1.48E-11
1775 1.57E-11
1800 1.66E-11
1825 1.76E-11
1850 1.86E-11
1875 1.96E-11
1900 2.06E-11
1925 2.17E-11
1931 2.20E-11