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Author(s):   Wilson, E.W.;Hamilton, W.A.;Mount, H.R.;DeMore, W.B.
Title:   Rate constants for the reactions of hydroxyl radical with several fluoroethers by the relative rate method
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   1610 - 1617
Year:   2007
Reference type:   Journal article
Squib:   2007WIL/HAM1610-1617

Reaction:   CF3OCF2CHF2 + ·OH → Products
Reaction order:   2
Temperature:   273 - 406 K
Pressure:  1.01 bar
Rate expression:   5.24x10-13 [±2.9x10-14 cm3/molecule s] e-13702 [±150 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   GC-MS
Comments:   Relative rates method was used with two reference compounds: CF3CF2H and CF3CHFCF3. Error limits are one standard deviation and do not reflect possible systematic uncertainties.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 1.25E-15
275 1.31E-15
300 2.16E-15
325 3.29E-15
350 4.73E-15
375 6.47E-15
400 8.51E-15
406 9.05E-15