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Author(s):   Yang, J.; Zhang, S.W.; Li, Q.S.
Title:   Reaction path dynamics and theoretical rate constants calculation for CHnF4-n+O3 -> HOOO+CHn-1F4-n(n=2,3) reactions
Journal:   Chem. J. Chin. Univ.
Volume:   28
Page(s):   1975 - 1977
Year:   2007
Reference type:   Journal article
Squib:   2007YAN/ZHA1975-1977

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2007YAN/ZHA1975-1977   CH3F + O3 → HO3 + ·CH2F  200 - 2500   6.55E-20   5.81   1.16E05   2.81E-40  2
  2007YAN/ZHA1975-1977   CH3F + O3 → HO3 + ·CH2F  200 - 2500   6.79E-20   5.97   1.21E05   4.52E-41  2
  2007YAN/ZHA1975-1977   CH2F2 + O3 → HO3 + ·CHF2  200 - 2500   1.76E-20   6.42   1.28E05   5.32E-43  2
  2007YAN/ZHA1975-1977   CH2F2 + O3 → HO3 + ·CHF2  200 - 2500   1.19E-20   6.45   1.29E05   3.44E-43  2
Search returned 4 records.