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Accessibility information
Author(s):   Asatryan, R.; Bozzelli, J.W.
Title:   Formation of a Criegee intermediate in the low-temperature oxidation of dimethyl sulfoxide
Journal:   Phys. Chem. Chem. Phys.
Volume:   10
Page(s):   1769 - 1780
Year:   2008
Reference type:   Journal article
Squib:   2008ASA/BOZ1769-1780

Reaction:   CH2(·)S(=O)CH2OOH → CH2(OH)S(·)=O + CH2O
Reaction order:   1
Temperature:   300 - 1000 K
Pressure:  1.01 bar
Rate expression:   1.05x1012 [s-1] (T/298 K)0.71 e-83345 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 3.23E-3
350 4.27E-1
400 1.68E1
450 2.96E2
500 2.96E3
550 1.96E4
600 9.53E4
650 3.65E5
700 1.16E6
750 3.16E6
800 7.62E6
850 1.66E7
900 3.33E7
950 6.22E7
1000 1.09E8