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Author(s):   Aschmann, S.M.; Long, W.D.; Atkinson, R.
Title:   Constants for the gas-phase reactions of OH radicals with dimethyl phosphonate over the temperature range of 278-351 K and for a series of other organophosphorus compounds at similar to 280 K
Journal:   J. Phys. Chem. A
Volume:   112
Page(s):   4793 - 4799
Year:   2008
Reference type:   Journal article
Squib:   2008ASC/LON4793-4799

Reaction:   ·OH + (CH3O)2P(O)C2H5 → Products
Reaction order:   2
Reference reaction:   iso-C4H9COCH3 + ·OH → Products
Temperature:   278 K
Pressure:  1.01 bar
Rate expression:   2.54x10-11 [±1.6x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography

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