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Accessibility information
Author(s):   Aschmann, S.M.; Tuazon, E.C.; Long, W.D.; Atkinson, R.
Title:   Kinetics and products of the gas-phase reactions of divinyl sulfoxide with OH and NO3 radicals and O3
Journal:   J. Phys. Chem. A
Volume:   112
Page(s):   8723 - 8730
Year:   2008
Reference type:   Journal article
Squib:   2008ASC/TUA8723-8730

Reaction:   Vinyl sulfoxide + ·OH → Products
Reaction order:   2
Reference reaction:   alpha-pinene + ·OH → Products
Temperature:   277 - 349 K
Pressure:  0.98 bar
Rate expression:   4.17x10-12 [cm3/molecule s] e7134 [J/mole]/RT
Category:  Experiment
Data type:   Experimental value and limited review
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
277 9.23E-11
300 7.28E-11
325 5.84E-11
349 4.87E-11