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Author(s):   Becerra, R.; Boganov, S.E.; Egorov, M.P.; Faustov, V.I.; Krylova, I.V.; Nefedov, O.M.; Promyslov, V.M.; Walsh, R.
Title:   Surprisingly slow reaction of dimethylsilylene with dimethylgermane: Time-resolved kinetic studies and related quantum chemical calculations
Journal:   J. Phys. Chem. A
Volume:   112
Page(s):   849 - 857
Year:   2008
Reference type:   Journal article
Squib:   2008BEC/BOG849-857

Reaction:   CH3GeH3 + SiH2 → Products
Reaction order:   2
Temperature:   296 K
Pressure:  1.33E-2 bar
Rate expression:   4.41x10-10 [±7.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

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