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Accessibility information
Author(s):   Du, S.Y.; Francisco, J.S.; Shepler, B.C.; Peterson, K.A.
Title:   Determination of the rate constant for sulfur recombination by quasiclassical trajectory calculations
Journal:   J. Chem. Phys.
Volume:   128
Page(s):  
Year:   2008
Reference type:   Journal article
Squib:   2008DU/FRA204306

Reaction:   S2S + S
Reaction order:   2
Temperature:   100 - 500 K
Pressure:  1.01 bar
Rate expression:   8.97x10-9 [cm3/molecule s] e-421494 [J/mole]/RT
Category:  Theory
Data type:   Other theoretical
Comments:   The rate constant was determined from quasiclassical trajectory calculations.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
100 6.19E-229
125 6.66E-185
150 1.51E-155
175 1.40E-134
200 7.45E-119
225 1.27E-106
250 7.73E-97
275 7.84E-89
300 3.68E-82
325 1.63E-76
350 1.12E-71
375 1.75E-67
400 8.17E-64
425 1.41E-60
450 1.07E-57
475 4.01E-55
500 8.33E-53