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Author(s):   Eskola, A.J.; Timonen, R.S.; Marshall, P.; Chesnokov, E.N.; Krasnoperov, L.N.
Title:   Rate constants and hydrogen isotope substitution effects in the CH3+HCl and CH3+Cl2 reactions
Journal:   J. Phys. Chem. A
Volume:   112
Page(s):   7391 - 7401
Year:   2008
Reference type:   Journal article
Squib:   2008ESK/TIM7391-7401

Reaction:   ·CH3 + Cl2CH3Cl + ·Cl
Reaction order:   2
Temperature:   188 - 500 K
Pressure:  8.00E-4 - 6.80E-3 bar
Rate expression:   1.67x10-13 [cm3/molecule s] (T/298 K)2.52 e5520 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
188 1.79E-12
200 1.69E-12
225 1.57E-12
250 1.53E-12
275 1.53E-12
300 1.55E-12
325 1.60E-12
350 1.67E-12
375 1.75E-12
400 1.85E-12
425 1.95E-12
450 2.07E-12
475 2.19E-12
500 2.32E-12