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Author(s):   Ide, T.; Nakayama, T.; Takahashi, K.; Matsumi, Y.
Title:   Thermal decomposition rate of N2O5 measured by cavity ring-down spectroscopy
Journal:   Int. J. Chem. Kinet.
Volume:   40
Page(s):   679 - 684
Year:   2008
Reference type:   Journal article
Squib:   2008IDE/NAK679-684

Reaction:   N2O5NO2 + NO3
Reaction order:   1
Temperature:   314 - 348 K
Pressure:  1.01 bar
Rate expression:   1.11x1015 [s-1] e-93122 [±10809 J/mole]/RT
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate
Experimental procedure:   Static or low flow - Data taken vs time
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
314 3.59E-1
325 1.20E0
348 1.17E1