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Accessibility information
Author(s):   Marquez, E.; Tosta, M.; Dominguez, R.M.; Herize, A.; Chuchani, G.
Title:   Mechanisms of the homogeneous, unimolecular gas-phase elimination kinetics of triethyl orthoacetate and triethyl orthopropionate
Journal:   J. Phys. Org. Chem.
Volume:   21
Page(s):   666 - 669
Year:   2008
Reference type:   Journal article
Squib:   2008MAR/TOS666-669

Reaction:   Propane, 1,1,1-triethoxy-C2H5OH + C2H4 + C2H5COOC2H5
Reaction order:   1
Temperature:   564 - 624 K
Pressure:  0.11 - 0.23 bar
Rate expression:   4.27x1013 [±7.0x1011 s-1] e-193300 [±1800 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
564 5.35E-5
575 1.18E-4
600 6.35E-4
624 2.82E-3