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Author(s):   Mora, J.R.; Dominguez, R.M.; Herize, A.; Tosta, M.; Chuchani, G.
Title:   Kinetics and mechanisms of gas-phase elimination of 2,2-diethoxyethyl amine and 2,2-diethoxy-N,N-diethylethanamine
Journal:   J. Phys. Org. Chem.
Volume:   21
Page(s):   359 - 364
Year:   2008
Reference type:   Journal article
Squib:   2008MOR/DOM359-364

Reaction:   Diethylaminoacetaldehyde diethyl acetal → C2H5OCH=CHN(C2H5)2 + C2H5OH
Reaction order:   1
Temperature:   593 - 653 K
Pressure:  5.33E-2 - 0.20 bar
Rate expression:   8.7x1013 [±5.0x1013 s-1] e-202300 [±2400 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
593 1.32E-4
600 2.13E-4
625 1.08E-3
650 4.82E-3
653 5.72E-3