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Author(s):   Skorobogatov, G.A.; Khripun, V.K.; Rebrova, A.G.
Title:   Isochoric isothermal pyrolysis of trifluoroiodomethane: CF3 recombination kinetics
Journal:   Kinet. Catal.
Volume:   49
Page(s):   466 - 473
Year:   2008
Reference type:   Journal article
Squib:   2008SKO/KHR466-473

Reaction:   ·CF3 + ·CF3C2F6
Reaction order:   2
Temperature:   300 - 1300 K
Pressure:  3.89E-2 - 0.40 bar
Rate expression:   1.1x10-11 [±5.18x10-13 cm3/molecule s] (T/298 K)0.50
Category:  Experiment
Data type:   Experimental value and limited review
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   GC-MS

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.10E-11
400 1.27E-11
500 1.42E-11
600 1.56E-11
700 1.68E-11
800 1.80E-11
900 1.91E-11
1000 2.01E-11
1100 2.11E-11
1200 2.20E-11
1300 2.29E-11