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Accessibility information
Author(s):   Smirnov, V.N.
Title:   Rate constant of the gas-phase reaction between Fe atoms and CO2
Journal:   Kinet. Catal.
Volume:   49
Page(s):   607 - 609
Year:   2008
Reference type:   Journal article
Squib:   2008SMI607-609

Reaction:   CO2 + FeCO + FeO
Reaction order:   2
Temperature:   1180 - 2380 K
Pressure:  4.22E13 - 6.02E13 bar
Rate expression:   2.32x10-10 [cm3/molecule s] e-121308 [±9146 J/mole]/RT
Uncertainty:   2.0
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1180 9.92E-16
1200 1.22E-15
1300 3.11E-15
1400 6.92E-15
1500 1.39E-14
1600 2.55E-14
1700 4.36E-14
1800 7.02E-14
1900 1.08E-13
2000 1.58E-13
2100 2.23E-13
2200 3.06E-13
2300 4.09E-13
2380 5.06E-13