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Accessibility information
Author(s):   Sun, J.Y.; Tang, Y.Z.; Sun, H.; Pan, Y.R.; Jia, X.J.; Pan, X.M.; Wang, R.S.
Title:   Mechanistic and kinetic study of the OH+C2H5CN reaction
Journal:   Chem. Phys. Lett.
Volume:   463
Page(s):   315 - 321
Year:   2008
Reference type:   Journal article
Squib:   2008SUN/TAN315-321

Reaction:   C2H5CN + ·OHH2O + N=C-CH2CH2
Reaction order:   2
Temperature:   150 - 3000 K
Pressure:  6.67E-2 bar
Rate expression:   6.54x10-15 [cm3/molecule s] (T/298 K)3.87 e416 [J/mole]/RT
Category:  Experiment
Data type:   Transition state theory
Comments:   The analytical rate expression given in the database has been calculated at NIST from the rate constants reported by the authors. The analytical expression has a maximum deviation of 12% from the individual values reported in the paper.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
150 6.41E-16
200 1.80E-15
300 7.93E-15
400 2.32E-14
500 5.36E-14
600 1.07E-13
700 1.91E-13
800 3.18E-13
900 4.98E-13
1000 7.44E-13
1100 1.07E-12
1200 1.49E-12
1300 2.03E-12
1400 2.70E-12
1500 3.51E-12
1600 4.50E-12
1700 5.68E-12
1800 7.08E-12
1900 8.71E-12
2000 1.06E-11
2100 1.28E-11
2200 1.53E-11
2300 1.82E-11
2400 2.14E-11
2500 2.50E-11
2600 2.91E-11
2700 3.37E-11
2800 3.87E-11
2900 4.43E-11
3000 5.05E-11