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Author(s):   Wang, L.; Liu, J.Y.; Li, Z.S.
Title:   Ab initio direct dynamics studies on the hydrogen abstraction reactions of CF2H2 and CF3H with F atom
Journal:   Chem. Phys.
Volume:   351
Page(s):   154 - 158
Year:   2008
Reference type:   Journal article
Squib:   2008WAN/LIU154-158

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2008WAN/LIU154-158   CH2F2 + ·F·CHF2 + HF  182 - 2000   4.00E-12   2.10   129   3.80E-12  2
  2008WAN/LIU154-158   CHF3 + ·F·CHF2 + HF  182 - 2000   5.34E-13   2.69   4141   1.00E-13  2

Search returned 2 records.