Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Yasunaga, K.; Kuraguchi, Y.; Hidaka, Y.; Takahashi, O.; Yamada, H.; Koike, T.
Title:   Kinetic and modeling studies on ETBE pyrolysis behind reflected shock waves
Journal:   Chem. Phys. Lett.
Volume:   451
Page(s):   192 - 197
Year:   2008
Reference type:   Journal article
Squib:   2008YAS/KUR192-197

Reaction:   tert-C4H9OC2H5C2H4 + tert-C4H9OH
Reaction order:   1
Temperature:   1000 - 1500 K
Pressure:  1.01 - 9.12 bar
Rate expression:   5.0x1013 [s-1] e-265000 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 7.20E-1
1050 3.28E0
1100 1.30E1
1150 4.60E1
1200 1.46E2
1250 4.22E2
1300 1.13E3
1350 2.79E3
1400 6.48E3
1450 1.42E4
1500 2.96E4