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Author(s):   Yasunaga, K.; Kuraguchi, Y.; Hidaka, Y.; Takahashi, O.; Yamada, H.; Koike, T.
Title:   Kinetic and modeling studies on ETBE pyrolysis behind reflected shock waves
Journal:   Chem. Phys. Lett.
Volume:   451
Page(s):   192 - 197
Year:   2008
Reference type:   Journal article
Squib:   2008YAS/KUR192-197

Reaction:   tert-C4H9OC2H5 → (CH3)2C(·)OCH2CH3 + ·CH3
Reaction order:   1
Temperature:   1000 - 1500 K
Pressure:  1.01 - 9.12 bar
Rate expression:   2.5x1016 [s-1] e-337000 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 6.24E-2
1050 4.30E-1
1100 2.49E0
1150 1.23E1
1200 5.36E1
1250 2.07E2
1300 7.20E2
1350 2.29E3
1400 6.68E3
1450 1.81E4
1500 4.60E4