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Author(s):   Blanco, M.B.; Bejan, I.; Barnes, I.; Wiesen, P.; Teruel, M.A.
Title:   OH-Initiated Degradation of Unsaturated Esters in the Atmosphere: Kinetics in the Temperature Range of 287-313 K
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   5958 - 5965
Year:   2009
Reference type:   Journal article
Squib:   2009BLA/BEJ5958-5965

Reaction:   CH3CO2CH=CH2 + ·OH → Products
Reaction order:   2
Temperature:   287 - 313 K
Pressure:  1.01 bar
Rate expression:   4.06x10-12 [±2.02x10-12 cm3/molecule s] e4490 [±407 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Error limits are 2 sigma (statistical). 1-butene and isobutene were used as reference compounds.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
287 2.66E-11
300 2.46E-11
313 2.28E-11