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Accessibility information
Author(s):   Brudnik, K.; Wojcik-Pastuszka, D.; Jodkowski, J.T.
Title:   Theoretical Analysis of the Kinetics of the Reaction of Methyl Mercaptan with Nitrogen Dioxide in the Gas Phase
Journal:   Pol. J. Chem.
Volume:   83
Page(s):   1203 - 1221
Year:   2009
Reference type:   Journal article
Squib:   2009BRU/WOJ1203-1221

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2009BRU/WOJ1203-1221   CH3SH + NO2CH3 + HNO2  200 - 500   7.80E-15   1.90   6.81E04   9.04E-27  2
  2009BRU/WOJ1203-1221   CH3SH + NO2HNO2 + ·CH2SH  200 - 500   5.92E-13   1.94   1.35E05   1.08E-36  2
  2009BRU/WOJ1203-1221   CH3 + HNO2CH3SH + NO2  200 - 500   5.04E-15   1.82   3.46E04   4.36E-21  2
  2009BRU/WOJ1203-1221   HNO2 + ·CH2SHCH3SH + NO2  200 - 500   4.08E-13   0.80   6.68E04   7.82E-25  2
  2009BRU/WOJ1203-1221   CH3 + CH3(CH3S)2  200 - 500   3.99E-11   0.20       3.99E-11  2
  2009BRU/WOJ1203-1221   CH3 + ·CH2SHCH3SCH2SH  200 - 500   1.20E-10   0.15       1.20E-10  2
  2009BRU/WOJ1203-1221   ·CH2SH + ·CH2SH(HS)CH2CH2(SH)  200 - 500   6.69E-11   0.19       6.69E-11  2
  2009BRU/WOJ1203-1221   (CH3S)2CH3 + CH3  200 - 500   2.22E18   -1.65   2.66E05   5.50E-29  1
  2009BRU/WOJ1203-1221   CH3SCH2SHCH3 + ·CH2SH  200 - 500   3.92E18   -0.64   2.76E05   1.91E-30  1
  2009BRU/WOJ1203-1221   (HS)CH2CH2(SH)·CH2SH + ·CH2SH  200 - 500   4.19E18   0.38   3.25E05   3.81E-39  1
  2009BRU/WOJ1203-1221   CH3SNO2CH3 + NO2  200 - 500   5.25E17   -1.32   1.71E05   5.52E-13  1
  2009BRU/WOJ1203-1221   HSCH2NO2NO2 + ·CH2SH  200 - 500   2.22E18   -1.65   2.66E05   5.50E-29  1
  2009BRU/WOJ1203-1221   NO2 + ·CH2SH → HSCH2NO2  200 - 500   2.60E-11   0.23       2.60E-11  2
  2009BRU/WOJ1203-1221   CH3 + NO2 → CH3SNO2  200 - 500   1.30E-11   0.19       1.30E-11  2

Search returned 14 records.