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Accessibility information
Author(s):   Bryukov, M.G.; Knyazev, V.D.; Gehling, W.M.; Dellinger, B.
Title:   Kinetics of the Gas-Phase Reaction of OH with Chlorobenzene
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   10452 - 10459
Year:   2009
Reference type:   Journal article
Squib:   2009BRY/KNY10452-10459

Reaction:   Chlorobenzene + ·OH → Products
Reaction order:   2
Temperature:   474 - 670 K
Pressure:  0.13 - 0.40 bar
Rate expression:   1.01x10-11 [±3.5x10-12 cm3/molecule s] e-20703 [±1413 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   The bimolecular rate constants demonstrate different behavior at low and high temperatures. This Arrhenius expression reproduces the experimental data with the maximum and average square deviations being 7.5 and 4.4%, respectively.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
474 5.28E-14
475 5.34E-14
500 6.94E-14
525 8.80E-14
550 1.09E-13
575 1.33E-13
600 1.59E-13
625 1.88E-13
650 2.19E-13
670 2.46E-13