Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Chen, L.; Uchimaru, T.; Mizukado, J.; Kutsuna, S.; Tokuhashi, K.; Sekiya, A.
Title:   Kinetics of the Gas-Phase Reactions of Cyclo-CF2 CFXCHXCHX-(X = H, F, Cl) with OH Radicals at 253-328 K
Journal:   Int. J. Chem. Kinet.
Volume:   41
Page(s):   532 - 542
Year:   2009
Reference type:   Journal article
Squib:   2009CHE/UCH532-542

Reaction:   cis-cyclo-CF2CFClCHClCH2 + ·OH → Products
Reaction order:   2
Temperature:   298 K
Pressure:  0.44 - 0.53 bar
Rate expression:   5.21x10-13 [±8.8x10-14 cm3/molecule s] e-5238 [±416 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Trans-cyclo-CF2CF2CHClCHCl and cis-cyclo-CF2CF2CHFCHF were used as reference compounds. The errors reported are ±2 standard deviations, and represent precision only.

View full bibliographic record.