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Author(s):   Chen, L.; Uchimaru, T.; Mizukado, J.; Kutsuna, S.; Tokuhashi, K.; Sekiya, A.
Title:   Kinetics of the Gas-Phase Reactions of Cyclo-CF2 CFXCHXCHX-(X = H, F, Cl) with OH Radicals at 253-328 K
Journal:   Int. J. Chem. Kinet.
Volume:   41
Page(s):   532 - 542
Year:   2009
Reference type:   Journal article
Squib:   2009CHE/UCH532-542

Reaction:   cis-cyclo-CF2CFClCHClCH2 + ·OH → Products
Reaction order:   2
Temperature:   298 K
Pressure:  0.44 - 0.53 bar
Rate expression:   5.21x10-13 [±8.8x10-14 cm3/molecule s] e-5238 [±416 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Trans-cyclo-CF2CF2CHClCHCl and cis-cyclo-CF2CF2CHFCHF were used as reference compounds. The errors reported are ±2 standard deviations, and represent precision only.

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