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Author(s):   Cometto, P.M.; Daele, V.; Idir, M.; Lane, S.I.; Mellouki, A.
Title:   Reaction Rate Coefficients of OH Radicals and Cl Atoms with Ethyl Propanoate, n-Propyl Propanoate, Methyl 2-Methylpropanoate, and Ethyl n-Butanoate
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   10745 - 10752
Year:   2009
Reference type:   Journal article
Squib:   2009COM/DAE10745-10752

Reaction:   C2H5C(O)OCH2CH2CH3 + ·Cl → Products
Reaction order:   2
Temperature:   296 K
Pressure:  1.01 bar
Rate expression:   8.2x10-11 [±4.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The errors quoted are twice the standard deviation arising from the average of the values obtained in the independent experiments and do not include the corresponding statistical error in the reference rate constant. The uncertainties in the rate coefficients do not take into account potential systematic errors in the reference rate constants, which could be as high as 15-20%. Ethane and propane were used as reference compounds.

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