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©NIST, 2013
Accessibility information
Author(s):   da Silva, G.; Bozzelli, J.W.
Title:   Kinetic modeling of the benzyl + HO2 reaction
Journal:   Proc. Combust. Inst.
Volume:   32
Page(s):   287 - 294
Year:   2009
Reference type:   Journal article
Squib:   2009DAS/BOZ287-294

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2009DAS/BOZ287-294   Benzyl + HO2 → C6H5CH2OOH  300 - 2000   3.78E-14   2.20   -2.15E04      2
  2009DAS/BOZ287-294   C6H5CH2OOH → Benzyl + HO2  300 - 2000   3.26E14   0.30   2.35E05      1
  2009DAS/BOZ287-294   C6H5CH2OOH → Benzaldehyde + H2O  300 - 2000   6.55E11   1.19   1.93E05      1
  2009DAS/BOZ287-294   C6H5CH2OOH → CH2O + Benzyne + H2O  300 - 2000   8.13E11   1.83   2.39E05      1
  2009DAS/BOZ287-294   C6H5CH2OOH → ·OH + C6H5CH2O  300 - 2000   2.74E11   0.98   2.26E05      1
  2009DAS/BOZ287-294   C6H5CH2OOH → ·OH + C6H5CH2O  300 - 2000   3.60E14   0.42   1.67E05      1
  2009DAS/BOZ287-294   C6H5CH2OOH → C6H5CHOH + ·OH  300 - 2000   4.32E12   1.37   2.11E05      1
  2009DAS/BOZ287-294   Benzyl + HO2·OH + C6H5CH2O  300 - 800   1.85E-13   4.92   1.05E04      2
  2009DAS/BOZ287-294   Benzyl + HO2·OH + C6H5CH2O  800 - 2000   6.99E-13   1.03   -9414      2
  2009DAS/BOZ287-294   Benzyl + HO2 → C6H5CH2OOH  300 - 700   6.27E-13   0.02   -1.45E04      2
  2009DAS/BOZ287-294   Benzyl + HO2 → C6H5CH2OOH  700 - 2000   2.42E-27   -16.33   -2.82E05      2

Search returned 11 records.