Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   da Silva, G.; Bozzelli, J.W.
Title:   Benzoxyl Radical Decomposition Kinetics: Formation of Benzaldehyde plus H, Phenyl + CH2O, and Benzene plus HCO
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   6979 - 6986
Year:   2009
Reference type:   Journal article
Squib:   2009DAS/BOZ6979-6986

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2009DAS/BOZ6979-6986   C6H5CH2O → Benzaldehyde +   298 - 2000   1.41E16   -5.08   9.31E04   0.68  1
  2009DAS/BOZ6979-6986   C6H5CH2O → CH2O + Phenyl  298 - 2000   3.11E18   -6.21   1.54E05   2.94E-09  1
  2009DAS/BOZ6979-6986   C6H5CH2O → Benzene + HCO  298 - 2000   1.97E17   -6.09   1.21E05   1.47E-04  1
  2009DAS/BOZ6979-6986   C6H5CH2O → Benzaldehyde +   298 - 2000   3.67E12   1.56   7.05E04   1.61  1
  2009DAS/BOZ6979-6986   Benzaldehyde + → C6H5CH2O  298 - 2000   4.44E-12   1.67   1.95E04   1.73E-15  2
  2009DAS/BOZ6979-6986   Benzaldehyde + → C6H5CHOH  298 - 2000   1.73E-12   1.77   1.90E04   8.22E-16  2
  2009DAS/BOZ6979-6986   C6H5CHOH → Benzaldehyde +   298 - 2000   1.83E12   1.28   1.54E05   1.79E-15  1
  2009DAS/BOZ6979-6986   C6H5CH2O → C6H5CHOH  298 - 2000   6.35E08   4.26   8.31E04   1.73E-06  1
  2009DAS/BOZ6979-6986   C6H5CHOH → C6H5CH2O  298 - 2000   8.11E08   3.88   1.67E05   4.01E-21  1
  2009DAS/BOZ6979-6986   C6H5CH2O → 2,5-cyclohexadien-4-formyl-1-yl  298 - 2000   5.64E11   1.43   8.06E04   4.23E-03  1
  2009DAS/BOZ6979-6986   2,5-cyclohexadien-4-formyl-1-yl → C6H5CH2O  298 - 2000   2.25E-05   1.15   1.03E05   2.27E-23  1
  2009DAS/BOZ6979-6986   C6H5CH2O → 1-oxaspiro[2.5]octa-4,7-dien-5-yl  298 - 2000   1.13E12   0.40   4.67E04   7263  1
  2009DAS/BOZ6979-6986   1-oxaspiro[2.5]octa-4,7-dien-5-yl → C6H5CH2O  298 - 2000   1.06E13   -0.03   7029   6.24E11  1
  2009DAS/BOZ6979-6986   1-oxaspiro[2.5]octa-4,7-dien-5-yl → C6H5OCH2  298 - 2000   1.19E13   0.23   4.06E04   9.02E05  1
  2009DAS/BOZ6979-6986   C6H5OCH2 → 1-oxaspiro[2.5]octa-4,7-dien-5-yl  298 - 2000   1.09E12   0.44   7.96E04   0.01  1
  2009DAS/BOZ6979-6986   2,5-cyclohexadien-4-formyl-1-yl → Benzaldehyde +   298 - 2000   2.46E11   1.60   9.85E04   1.32E-06  1
  2009DAS/BOZ6979-6986   C6H5CH2O → CH2O + Phenyl  298 - 2000   2.67E14   0.16   1.30E05   3.75E-09  1
  2009DAS/BOZ6979-6986   C6H5OCH2CH2O + Phenyl  298 - 2000   3.55E14   0.05   1.64E05   5.54E-15  1
  2009DAS/BOZ6979-6986   2,5-cyclohexadien-4-formyl-1-yl → Benzene + HCO  298 - 2000   2.48E13   0.23   7.20E04   5.82  1
  2009DAS/BOZ6979-6986   Benzene + HCO → 2,5-cyclohexadien-4-formyl-1-yl  298 - 2000   2.10E-15   2.79   4.63E04   1.60E-23  2
  2009DAS/BOZ6979-6986   CH2O + Phenyl → C6H5OCH2  298 - 2000   7.15E-15   2.69   5.41E04   2.36E-24  2
  2009DAS/BOZ6979-6986   CH2O + Phenyl → C6H5CH2O  298 - 2000   4.62E-15   2.57   1.94E04   1.86E-18  2
  2009DAS/BOZ6979-6986   Benzaldehyde + → 2,5-cyclohexadien-4-formyl-1-yl  298 - 2000   7.38E-13   1.98   2.54E04   2.61E-17  2

Search returned 23 records.