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Author(s):   Giri, B.R.; Roscoe, J.M.
Title:   Temperature Dependence of the Rate Coefficients for the Reactions of Atomic Bromine with Toluene, Tetrahydrofuran, and Tetrahydropyran
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   8001 - 8010
Year:   2009
Reference type:   Journal article
Squib:   2009GIR/ROS8001-8010

Reaction:   Toluene + Br· → Products
Reaction order:   2
Reference reaction:   iso-C4H10 + Br· → Products
Temperature:   302 - 352 K
Pressure:  1.01 - 1.01 bar
Rate expression:   3.7x10-12 [±1.7x10-12 cm3/molecule s] e-13553 [±1247 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Experiments were performed in a bath of argon containing unspecified but varied amount of oxygen. The uncertainties represent one standard deviation.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
302 1.68E-14
325 2.45E-14
350 3.51E-14
352 3.61E-14