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Accessibility information
Author(s):   Goldsmith, C.F.; Ismail, H.; Green, W.H.
Title:   Pressure and Temperature Dependence of the Reaction of Vinyl Radical with Alkenes III: Measured Rates and Predicted Product Distributions for Vinyl plus Butene
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   13357 - 13371
Year:   2009
Reference type:   Journal article
Squib:   2009GOL/ISM13357-13371

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2009GOL/ISM13357-13371   1-C4H8 + C2H3 → Products  292 - 700   1.30E-12       1.83E04   8.09E-16  2
  2009GOL/ISM13357-13371   1-C4H8 + C2H3 → Products  292 - 700   1.15E-13   1.70   1.19E04   9.47E-16  2
  2009GOL/ISM13357-13371   CH3CH=CHCH3 + C2H3 → Products  292 - 700   1.15E-13   1.70   1.46E04   3.24E-16  2
  2009GOL/ISM13357-13371   iso-C4H8 + C2H3 → Products  292 - 700   1.02E-13   1.70   1.19E04   8.42E-16  2
  2009GOL/ISM13357-13371   iso-C4H8 + C2H3 → Products  292 - 700   1.00E-12       1.77E04   7.87E-16  2
  2009GOL/ISM13357-13371   CH3CH=CHCH3 + C2H3 → Products  292 - 700   1.70E-12       2.17E04   2.67E-16  2
    2009GOL/ISM13357-13371   1-C4H8 + C2H3 → CH2=CHCH2C(·)HCH2CH3  400 - 2000                  2
    2009GOL/ISM13357-13371   1-C4H8 + C2H3 → CH2=CHCH(C2H5)CH2(·)  400 - 2000                  2
    2009GOL/ISM13357-13371   1-C4H8 + C2H3 → 2-ethyl-cyclopropylmethyl  400 - 2000                  2
    2009GOL/ISM13357-13371   1-C4H8 + C2H3C2H4 + CH2=CHCH(·)CH3  400 - 2000                  2
    2009GOL/ISM13357-13371   1-C4H8 + C2H3CH2=CHCH2CH=CH2 + ·CH3  400 - 2000                  2
    2009GOL/ISM13357-13371   1-C4H8 + C2H3 + (E)-CH2=CHCH=CHC2H5  400 - 2000                  2
    2009GOL/ISM13357-13371   1-C4H8 + C2H31,3-Butadiene + ·C2H5  400 - 2000                  2
    2009GOL/ISM13357-13371   1-C4H8 + C2H3CH3CH=CH2 + ·CH2CH=CH2  400 - 2000                  2
    2009GOL/ISM13357-13371   CH3CH=CHCH3 + C2H3 → CH2=CHC(·)(CH3)CH2CH3  400 - 2000                  2
    2009GOL/ISM13357-13371   CH3CH=CHCH3 + C2H3C2H4 + CH2=CHCH(·)CH3  400 - 2000                  2
    2009GOL/ISM13357-13371   CH3CH=CHCH3 + C2H3CH2=CHCH=CHCH3 + ·CH3  400 - 2000                  2
    2009GOL/ISM13357-13371   CH3CH=CHCH3 + C2H3CH2=CHC(CH3)=CHCH3 +   400 - 2000                  2
    2009GOL/ISM13357-13371   iso-C4H8 + C2H3 → CH2=CHCH2C(·)(CH3)2  400 - 2000                  2
    2009GOL/ISM13357-13371   iso-C4H8 + C2H3C2H4 + ·CH2C(CH3)=CH2  400 - 2000                  2
    2009GOL/ISM13357-13371   iso-C4H8 + C2H3CH2=C(CH3)CH=CH2 + ·CH3  400 - 2000                  2
    2009GOL/ISM13357-13371   iso-C4H8 + C2H3(CH3)2C=CHCH=CH2 +   400 - 2000                  2

Search returned 22 records.