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Author(s):   Herize, A.; Mora, J.R.; Lezama, J.; Marquez, E.; Cordova, T.; Chuchani, G.
Title:   Experimental and theoretical study of the mechanism for the kinetic of elimination of methyl carbazate in the gas phase
Journal:   J. Phys. Org. Chem.
Volume:   22
Page(s):   170 - 176
Year:   2009
Reference type:   Journal article
Squib:   2009HER/MOR170-176

Reaction:   Methyl carbazateCH3NH2 + CO + HNO
Reaction order:   1
Temperature:   613 - 663 K
Pressure:  6.27E-2 - 0.16 bar
Rate expression:   3.63x1011 [s-1] e-180700 [±4100 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Pressure measurement
Comments:   log(A/s-1) = 11.56 ± 0.34.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
613 1.47E-4
625 2.87E-4
650 1.09E-3
663 2.12E-3