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Author(s):   Hold, M.; Hoyermann, K.; Morozov, I.; Zeuch, T.
Title:   CH2Cl and CHCl2 Radical Chemistry: The Formation by the Reactions CH3Cl + F and CH2Cl2 + F and the Destruction by the Reactions CH2Cl + O and CHCl2 + O
Journal:   Z. Phys. Chem.
Volume:   223
Page(s):   409 - 426
Year:   2009
Reference type:   Journal article
Squib:   2009HOL/HOY409-426

Reaction:   CH3Cl + ·F·CH2Cl + HF
Reaction order:   2
Reference reaction:   CH4 + ·F·CH3 + HF
Temperature:   253 - 358 K
Pressure:  2.00E-3 bar
Rate expression:   3.04x10-11 [±6.14x10-12 cm3/molecule s] e197 [±510 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The error bars reflect the errors on the basis of the 95 % confidence level. The uncertainty in the rate constant of the reference reaction is not included.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
253 3.34E-11
275 3.31E-11
300 3.29E-11
325 3.27E-11
350 3.25E-11
358 3.25E-11