Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Hold, M.; Hoyermann, K.; Morozov, I.; Zeuch, T.
Title:   CH2Cl and CHCl2 Radical Chemistry: The Formation by the Reactions CH3Cl + F and CH2Cl2 + F and the Destruction by the Reactions CH2Cl + O and CHCl2 + O
Journal:   Z. Phys. Chem.
Volume:   223
Page(s):   409 - 426
Year:   2009
Reference type:   Journal article
Squib:   2009HOL/HOY409-426

Reaction:   CH3Cl + ·F·CH2Cl + HF
Reaction order:   2
Reference reaction:   CH4 + ·F·CH3 + HF
Temperature:   253 - 358 K
Pressure:  2.00E-3 bar
Rate expression:   3.04x10-11 [±6.14x10-12 cm3/molecule s] e197 [±510 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The error bars reflect the errors on the basis of the 95 % confidence level. The uncertainty in the rate constant of the reference reaction is not included.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
253 3.34E-11
275 3.31E-11
300 3.29E-11
325 3.27E-11
350 3.25E-11
358 3.25E-11