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Author(s):   Hold, M.; Hoyermann, K.; Morozov, I.; Zeuch, T.
Title:   CH2Cl and CHCl2 Radical Chemistry: The Formation by the Reactions CH3Cl + F and CH2Cl2 + F and the Destruction by the Reactions CH2Cl + O and CHCl2 + O
Journal:   Z. Phys. Chem.
Volume:   223
Page(s):   409 - 426
Year:   2009
Reference type:   Journal article
Squib:   2009HOL/HOY409-426

Reaction:   CHCl2 + CO + HCl + ·Cl
Reaction order:   2
Reference reaction:   CHCl2 + → Products
Reference reaction order:   2
Temperature:   258 - 358 K
Pressure:  2.00E-3 bar
Rate expression:   7.0x10-1
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The uncertainty in the branching fraction is not reported. ClCHO and ClCO products were detected but not quantified.

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