Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Nilsson, E.JK.; Nielsen, O.J.; Johnson, M.S.; Hurley, M.D.; Wallington, T.J.
Title:   Atmospheric chemistry of cis-CF3CH=CHF: Kinetics of reactions with OH radicals and O-3 and products of OH radical initiated oxidation
Journal:   Chem. Phys. Lett.
Volume:   473
Page(s):   233 - 237
Year:   2009
Reference type:   Journal article
Squib:   2009NIL/NIE233-237

Reaction:   (Z)-1,3,3,3-tetrafluoroprop-1-ene + ·OH → Products
Reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   1.2x10-12 [±1.4x10-13 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Ethylene and acetylene were used as reference compounds. The value given here is the average of the individual determinations with error limits which encompass the extremes of the determinations.

View full bibliographic record.