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Author(s):   Noda, J.; Volkamer, R.; Molina, M.J.
Title:   Dealkylation of Alkylbenzenes: A Significant Pathway in the Toluene, o-, m-, p-Xylene plus OH Reaction
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   9658 - 9666
Year:   2009
Reference type:   Journal article
Squib:   2009NOD/VOL9658-9666

Reaction:   Toluene + ·OH → methylphenol (unspecified isomer) +
Reaction order:   2
Reference reaction:   Toluene + ·OH → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  0.21 bar
Rate expression:   1.77x10-1±2.1x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The OH-radical initiated oxidation of a series of monocyclic aromatic hydrocarbons (benzene, toluene, o-, m-, and p-xylene) in the presence of oxygen and NOx was investigated in a flowtube coupled with a chemical ionization mass spectrometer.

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