Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Pokidova, T.S.; Denisov, E.T.; Shestakov, A.F.
Title:   Kinetic Parameters and Geometry of the Transition State of Acyl Radical Decarbonylation
Journal:   Kinet. Catal.
Volume:   50
Page(s):   647 - 655
Year:   2009
Reference type:   Journal article
Squib:   2009POK/DEN647-655

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2009POK/DEN647-655   CH3COCO + ·CH3  298   1.57E13       7.23E04   3.34  1
  2009POK/DEN647-655   CH3CH2COCO + ·C2H5  298   1.57E13       6.09E04   332  1
  2009POK/DEN647-655   CH3CH2CH2CO → CO + 1-C3H7  298   1.57E13       6.07E04   360  1
  2009POK/DEN647-655   CH3CH2CH2CH2CO· → CO + 1-C4H9  298   1.57E13       6.09E04   332  1
  2009POK/DEN647-655   iso-C4H9CO· → CO + iso-C4H9  298   1.57E13       6.55E04   51.88  1
  2009POK/DEN647-655   (CH3)2CHC=O → CO + iso-C3H7  298   1.57E13       5.25E04   9855  1
  2009POK/DEN647-655   C2H5CH(CH3)C(O)· → CO + sec-C4H9  298   1.57E13       5.34E04   6854  1
  2009POK/DEN647-655   (CH3)3CC(O)· → CO + tert-C4H9  298   1.57E13       4.06E04   1.20E06  1
  2009POK/DEN647-655   ·C(O)C(O)OH → HOCO + CO  298   1.57E13       4.06E04   1.20E06  1
  2009POK/DEN647-655   CH2(OH)CH(OH)CH(OH)CH(OH)CH(OH)C(·)O → CH2(OH)CH(OH)CH(OH)CH(OH)CH(·)OH + CO  298   1.57E13       4.72E04   8.37E04  1
  2009POK/DEN647-655   cyc-C6H11-C(·)O → CO + Cyclohexyl  298   1.57E13       5.13E04   1.60E04  1
  2009POK/DEN647-655   cyc-CH2CH2CH2CH2CH2C(CH3)(C(·)O) → cyc-CH2CH2CH2CH2CH2C(·)(CH3) + CO  298   1.57E13       3.92E04   2.11E06  1
  2009POK/DEN647-655   cyc-C5H9-C(·)O → CO + Cyclopentyl  298   1.57E13       4.68E04   9.84E04  1
  2009POK/DEN647-655   C6H5-CH2C(·)O → CO + Benzyl  298   1.57E13       3.42E04   1.59E07  1
  2009POK/DEN647-655   C6H5-CH(CH3)C(·)O → CO + 1-phenylethyl  298   1.57E13       3.27E04   2.91E07  1
  2009POK/DEN647-655   C6H5-C(CH3)2C(·)O → CO + 2-Phenyl-2-propyl radical  298   1.57E13       3.00E04   8.66E07  1
  2009POK/DEN647-655   CO + 2-Phenyl-2-propyl radical → C6H5-C(CH3)2C(·)O  298   2.99E-13       3.84E04   5.56E-20  2
  2009POK/DEN647-655   CO + 1-phenylethyl → C6H5-CH(CH3)C(·)O  298   2.99E-13       3.34E04   4.18E-19  2
  2009POK/DEN647-655   CO + Benzyl → C6H5-CH2C(·)O  298   2.99E-13       3.09E04   1.15E-18  2
  2009POK/DEN647-655   CO + Cyclopentyl → cyc-C5H9-C(·)O  298   2.99E-13       1.39E04   1.09E-15  2
  2009POK/DEN647-655   cyc-CH2CH2CH2CH2CH2C(·)(CH3) + CO → cyc-CH2CH2CH2CH2CH2C(CH3)(C(·)O)  298   2.99E-13       2.32E04   2.56E-17  2
  2009POK/DEN647-655   CO + Cyclohexyl → cyc-C6H11-C(·)O  298   2.99E-13       1.29E04   1.64E-15  2
  2009POK/DEN647-655   CH2(OH)CH(OH)CH(OH)CH(OH)CH(·)OH + CO → CH2(OH)CH(OH)CH(OH)CH(OH)CH(OH)C(·)O  298   2.99E-13       1.35E04   1.29E-15  2
  2009POK/DEN647-655   HOCO + CO → ·C(O)C(O)OH  298   2.99E-13       2.15E04   5.09E-17  2
  2009POK/DEN647-655   CO + tert-C4H9 → (CH3)3CC(O)·  298   2.99E-13       2.15E04   5.09E-17  2
  2009POK/DEN647-655   CO + sec-C4H9 → C2H5CH(CH3)C(O)·  298   2.99E-13       7300   1.57E-14  2
  2009POK/DEN647-655   CO + iso-C4H9 → iso-C4H9CO·  298   2.99E-13       1.24E04   2.00E-15  2
  2009POK/DEN647-655   CO + 1-C4H9 → CH3CH2CH2CH2CO·  298   2.99E-13       1.73E04   2.77E-16  2
  2009POK/DEN647-655   CO + iso-C3H7 → (CH3)2CHC=O  298   2.99E-13       8000   1.18E-14  2
  2009POK/DEN647-655   CO + 1-C3H7 → CH3CH2CH2CO  298   2.99E-13       1.75E04   2.56E-16  2
  2009POK/DEN647-655   CO + ·C2H5CH3CH2CO  298   2.99E-13       1.73E04   2.77E-16  2
  2009POK/DEN647-655   CO + ·CH3CH3CO  298   2.99E-13       2.54E04   1.06E-17  2

Search returned 32 records.