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Author(s):   Young, C.J.; Hurley, M.D.; Wallington, T.J.; Mabury, S.A.
Title:   Atmospheric chemistry of CF3CF2H and CF3CF2CF2CF2H: Kinetics and products of gas-phase reactions with Cl atoms and OH radicals, infrared spectra, and formation of perfluorocarboxylic acids
Journal:   Chem. Phys. Lett.
Volume:   473
Page(s):   251 - 256
Year:   2009
Reference type:   Journal article
Squib:   2009YOU/HUR251-256

Reaction:   C2F5H + Cl → Products
Reaction order:   2
Reference reaction:   CH3CF2Cl + Cl → Products
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   2.93x10-16 [±2.3x10-17 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Quoted uncertainties include two standard deviations from the linear least squares regression analysis and uncertainties associated with the IR analyses.

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