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Accessibility information
Author(s):   Awan, I.A.; McGivern, W.S.; Tsang, W.; Manion, J.A.
Title:   Decomposition and Isomerization of 5-Methylhex-1-yl Radical
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   7832 - 7846
Year:   2010
Reference type:   Journal article
Squib:   2010AWA/MCG7832-7846

Reaction:   (CH3)2CHCH2CH2CH2CH2I → I + (iso-C3H7)(CH2)3CH2·
Reaction order:   2
Temperature:   889 - 1001 K
Pressure:  1.60 - 2.00 bar
Rate expression:   7.76x1013 [cm3/molecule s] e-204952 [±4407 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Errors are given as the standard uncertainties (1σ) derived from the statistical fits. The uncertainty in the preexponential factor is expressed as follows: A = 10(13.89±0.24) s-1.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
889 7.04E1
900 9.89E1
925 2.07E2
950 4.18E2
975 8.13E2
1000 1.53E3
1001 1.57E3