Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Berteloite, C.; Le Picard, S.D.; Balucani, N.; Canosa, A.; Sims, I.R.
Title:   Low temperature rate coefficients for reactions of the butadiynyl radical, C4H, with various hydrocarbons. Part II: reactions with alkenes (ethylene, propene, 1-butene), dienes (allene, 1,3-butadiene) and alkynes (acetylene, propyne and 1-butyne)
Journal:   Phys. Chem. Chem. Phys.
Volume:   12
Page(s):   3677 - 3689
Year:   2010
Reference type:   Journal article
Squib:   2010BER/LEP3677-3689

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2010BER/LEP3677-3689   C2H4 + CH≡CC≡C → Products  39.00 - 300   1.95E-10   -0.40   78.16   1.89E-10  2
  2010BER/LEP3677-3689   CH3CH=CH2 + CH≡CC≡C → Products  39.00 - 300   3.25E-10   -0.84   407   2.76E-10  2
  2010BER/LEP3677-3689   1-C4H8 + CH≡CC≡C → Products  39.00 - 300   6.30E-10   -0.61   540   5.07E-10  2
  2010BER/LEP3677-3689   CH2=C=CH2 + CH≡CC≡C → Products  39.00 - 300   3.70E-10   -1.18   757   2.73E-10  2
  2010BER/LEP3677-3689   1,3-Butadiene + CH≡CC≡C → Products  39.00 - 300   5.37E-10   -1.25   971   3.63E-10  2
  2010BER/LEP3677-3689   C2H2 + CH≡CC≡C → Products  39.00 - 300   1.82E-10   -1.06   548   1.46E-10  2
  2010BER/LEP3677-3689   CH3CCH + CH≡CC≡C → Products  39.00 - 300   3.20E-10   -0.82   395   2.73E-10  2
  2010BER/LEP3677-3689   1-butyne + CH≡CC≡C → Products  39.00 - 300   3.48E-10   -0.65   486   2.86E-10  2

Search returned 8 records.