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Author(s):   Broadley, S.L.; Plane, J.MC.
Title:   A kinetic study of reactions of calcium-containing molecules with O and H atoms: implications for calcium chemistry in the upper atmosphere
Journal:   Phys. Chem. Chem. Phys.
Volume:   12
Page(s):   9095 - 9107
Year:   2010
Reference type:   Journal article
Squib:   2010BRO/PLA9095-9107

Reaction:   CaO2 + CaO + O2
Reaction order:   2
Temperature:   300 K
Pressure:  1.60E-3 bar
Rate expression:   2.2x10-11 [cm3/molecule s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Laser induced fluorescence
Comments:   The uncertainty is 1σ. The uncertainty is expressed as follows: k = (2.2 (+7.0/-1.4))x10-11 cm3 molecule-1 s-1.

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