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Author(s):   Chiappero, M.S.; Arguello, G.A.; Hurley, M.D.; Wallington, T.J.
Title:   Atmospheric Chemistry of n-C6F13CH2CHO: Formation from n-C6F13CH2CH2OH, Kinetics, and Mechanisms of Reactions with Chlorine Atoms and OH Radicals
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   6131 - 6137
Year:   2010
Reference type:   Journal article
Squib:   2010CHI/ARG6131-6137

Reaction:   ·OH + C6F13CH2CHO → Products
Reaction order:   2
Reference reaction:   C2H4 + ·OH → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   2.5x10-1±3.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Uncertainties include two standard deviations from least-squares regressions and uncertainties in the analysis of the IR spectra (typically 1% of original concentrations of the reactants).

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