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Author(s):   Cometto, P.M.; Taccone, R.A.; Nieto, J.D.; Dalmasso, P.R.; Lane, S.I.
Title:   Kinetic Study of OH Radical Reactions with CF3CCl=CCl2, CF3CCl=CClCF3 and CF3CF=CFCF3
Volume:   11
Page(s):   4053 - 4059
Year:   2010
Reference type:   Journal article
Squib:   2010COM/TAC4053-4059

Reaction:   CF3CCl=CClCF3 (unspecified isomer) + ·OH → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.00 bar
Rate expression:   2.1x10-13 [±2.0x10-14 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Acetone and ethane were used as reference compounds. The errors quoted are twice the statistical deviation arising from the average of the values obtained in the independent experiments and do not include uncertainties from reference rate constants. An additional 15% could be considered to take into account the experimental error.

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