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Accessibility information
Author(s):   da Silva, G.
Title:   Hydroxyl radical regeneration in the photochemical oxidation of glyoxal: kinetics and mechanism of the HC(O)CO + O2 reaction
Journal:   Phys. Chem. Chem. Phys.
Volume:   12
Page(s):   6698 - 6705
Year:   2010
Reference type:   Journal article
Squib:   2010DAS6698-6705

Reaction:   HC(O)CO → CO + HCO
Reaction order:   1
Temperature:   150 - 400 K
Pressure:  1.01E-2 - 1.01 bar
Rate expression:   no rate data available
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is pressure dependent
Comments:   Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated for wide ranges of temperatures and pressures using transition state theory, RRKM, and master equation. Rate constants for individual temperatures and pressures are presented in a graphical format.

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