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Author(s):   Friederich, L.; Duncan, J.R.; Heard, G.L.; Setser, D.W.; Holmes, B.E.
Title:   Unimolecular Reactions of CH2BrCH2Br, CH2BrCH2Cl, and CH2BrCD2Cl: Identification of the Cl-Br Interchange Reaction
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   4138 - 4147
Year:   2010
Reference type:   Journal article
Squib:   2010FRI/DUN4138-4147

Reaction:   ·CH2Cl + ·CH2BrCH2=CHCl + HBr
Reaction order:   2
Reference reaction:   ·CH2Cl + ·CH2BrCH2BrCH2Cl
Reference reaction order:   2
Temperature:   298 K
Pressure:  0.11 - 0.67 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Decomposition-to-stabilization ratio in chemically activated dissociation of 1-bromo-2-chloroethane was determined as a function of pressure. Data are presented in a graphical format.

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